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122440

噻蒽

Name: 噻蒽
Brand: ALDRICH

97%

别名:

二苯并二硫代二噁烷

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关于此项目

经验公式（希尔记法）:

C₁₂H₈S₂

化学文摘社编号:

92-85-3

分子量:

216.32

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24847488

EC Number:

202-197-0

Beilstein/REAXYS Number:

83046

MDL number:

MFCD00005065

Assay:

97%

Form:

solid

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属性

Quality Level

100

assay

97%

form

solid

bp

364-366 °C (lit.)

mp

151-155 °C (lit.)

solubility

DMF: soluble, H₂O: insoluble

SMILES string

S1c2ccccc2Sc3ccccc13

InChI

1S/C12H8S2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H

InChI key

GVIJJXMXTUZIOD-UHFFFAOYSA-N

说明

General description

在大孔沸石和中孔铝硅酸盐催化剂存在时，噻蒽可通过液相叔丁基化反应生成叔丁基衍生物。在过氧化氢和木质素酶作为来自黄孢原毛平革菌的催化剂存在时，噻蒽经氧化可生成噻蒽单亚砜。

Application

噻蒽已被用于研究蒽、菲和芴的几种固体含氮、硫和氧的杂环衍生物的水溶性。它已被用于测定1-己基-3-甲基咪唑双（三氟甲基磺酰基）酰亚胺和超临界二氧化碳中几种含硫芳烃的分配系数。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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Aqueous solubility data for pressurized hot water extraction for solid heterocyclic analogs of anthracene, phenanthrene and fluorene.

Pavel Karásek et al.

Journal of chromatography. A, 1140(1-2), 195-204 (2006-12-05)

We report the aqueous solubilities of phenanthrene and several solid three-ring aromatic heterocycles (phenanthridine, acridine, phenazine, thianthrene, phenothiazine, phenoxathiin, phenoxazine, carbazole, dibenzofuran, dibenzothiophene, and 4,6-dimethyldibenzothiophene) at temperatures ranging from 313K to the solute melting point and at a pressure of

Distribution of sulfur-containing aromatics between [hmim][Tf2N] and supercritical CO2: a case study for deep desulfurization of oil refinery streams by extraction with ionic liquids.

Planeta J, et al.

Green Chemistry, 8(1), 70-77 (2006)

Oxidation of Thianthrene by the Ligninase of Phanerochaete chrysosporium.

R P Schreiner et al.

Applied and environmental microbiology, 54(7), 1858-1860 (1988-07-01)

The oxidation of heterocyclic sulfur compounds reported to be part of the macrostructure of coal and petroleum was investigated. The oxidation of thianthrene solubilized in 10% dimethylformamide to thianthrene monosulfoxide in the presence of hydrogen peroxide was catalyzed by the

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货号	GTIN
122440-25G	04061838721235