140732
N,N-二甲基甲酰胺二甲缩醛
technical grade, 94%
别名:
1,1-二甲氧基-N,N-二甲氧基, 1,1-二甲氧基三甲胺
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关于此项目
线性分子式:
(CH3)2NCH(OCH3)2
化学文摘社编号:
分子量:
119.16
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
EC Number:
225-063-3
Beilstein/REAXYS Number:
506020
MDL number:
Assay:
94%
Form:
liquid
grade
technical grade
Quality Level
assay
94%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.396 (lit.)
bp
102-103 °C/720 mmHg (lit.)
density
0.897 g/mL at 25 °C (lit.)
functional group
amine, ether
SMILES string
COC(OC)N(C)C
InChI
1S/C5H13NO2/c1-6(2)5(7-3)8-4/h5H,1-4H3
InChI key
ZSXGLVDWWRXATF-UHFFFAOYSA-N
Application
N,N-二甲基甲酰胺二甲基缩醛(DMF-DMA)可用作：
- 有机催化剂，以通过芳乙烯与缺电子炔烃反应合成1,2-二取代-3,4-二氢萘。
- 基本构成要素，以通过亚甲基和氨基的甲酰化制备诸如烯胺和脒等杂环化合物。
- 一种试剂，以通过与氯代乙酰胺反应合成1,4-二芳基-哌嗪-2,5-二酮。
- 一种试剂，在Me3SiCl存在下，与烯胺和炔属烃一起通过三组分偶联反应制备2,3,4,5-四取代吡啶衍生物。
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
42.8 °F
flash_point_c
6 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Wim Schepens et al.
Organic letters, 8(19), 4247-4250 (2006-09-08)
A novel series of analogues of calcitriol (1) is developed featuring a spirocyclic central core resulting from C18/C21-connection and C15/C16-deletion (2a, 2b). The synthesis of the key intermediate involves an Eschenmoser rearrangement of an enantiomerically pure bromo-substituted cyclohexenol.
A highly efficient cycloaddition of vinylarenes with electron-deficient alkynes affording 1, 2-disubstituted-3, 4-dihydronaphthalenes catalysed by N, N-dimethylformamide dimethyl acetal
Jiang J-L, et al.
Organic & Biomolecular Chemistry, 5(12), 1854-1857 (2007)
Qingfen Zhang et al.
Journal of the American Society for Mass Spectrometry, 16(7), 1192-1203 (2005-06-01)
A fragmentation mechanism for the neutral loss of 73 Da from dimethylformamidine glutamine isobutyl ester is investigated. Understanding this mechanism will allow to improve the identification and quantification of 15N-labeled and unlabeled glutamine and the distinguishing of glutamine and glutamic
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 140732-100ML | 04061838733634 |
| 140732-25ML | 04061838733658 |
| 140732-2.5L | 04061838733641 |
| 140732-500ML | 04061838733665 |