Merck
CN

203548

Sigma-Aldrich

硝酸镧(III) 六水合物

99.999% trace metals basis

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别名:
硝酸,镧(III)盐,六水合物
线性分子式:
La(NO3)3 · 6H2O
CAS号:
分子量:
433.01
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

检测方案

99.999% trace metals basis

形式

solid

反应适用性

reagent type: catalyst
core: lanthanum

杂质

≤15.0 ppm Trace Rare Earth Analysis

mp

65-68 °C

SMILES字符串

[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

InChI key

GJKFIJKSBFYMQK-UHFFFAOYSA-N

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一般描述

硝酸镧六水合物是过渡金属催化剂,广泛用于许多有机转化反应,例如丙酮化合物的化学选择性脱保护,醇、酚和胺与乙酸酐的酰化,α-氨基腈类化合物的合成反应。也可作为前体制备镧基纳米粒子。

应用

硝酸镧六水合物可用作下列反应的催化剂:
  • α羰基化合物、胺类和TMSCN通过一锅三组分偶联作用合成α-氨基腈。
  • 醛合成缩醛和偕二乙酸酯(乙酰缩醛)。
  • 无溶剂条件合成双吲哚基甲烷。
也可用作起始原料,用于电化学合成LaMnO3薄膜和溶剂热法合成掺杂型硫氧化镧(La2O2S)。

特点和优势

  • 热稳定性
  • 低毒
  • 反应条件温和
  • 化学选择性
  • 低成本

警示用语:

Danger

危险声明

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 2

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

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J Tyler Mefford et al.
Physical chemistry chemical physics : PCCP, 21(6), 3327-3338 (2019-01-29)
Perovskite oxides are active room-temperature bifunctional oxygen electrocatalysts in alkaline media, capable of performing the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with lower combined overpotentials relative to their precious metal counterparts. However, their semiconducting nature necessitates the
Emanuela Mazzon et al.
Shock (Augusta, Ga.), 25(5), 515-521 (2006-05-09)
Small intestine permeability is frequently altered in inflammatory bowel diseases and may be caused by the translocation of intestinal toxins through leaky small intestine tight junctions (TJs) and adherence. Thus, the aim of the present study was to examine the
H G Nóblega et al.
Comparative biochemistry and physiology. Part A, Molecular & integrative physiology, 144(1), 119-124 (2006-04-11)
The aim of this study was to investigate the ultrastructure of the interface zone between the nervous tissue and the connective vascular sheath that surround the central ganglia of the terrestrial snail of Megalobulimus abbreviatus and test its permeability using
Juan C Caraballo et al.
Respirology (Carlton, Vic.), 16(2), 340-349 (2010-12-03)
Inhaled particulate matter (PM) causes lung inflammation and epithelial dysfunction. However, the direct effect of PM on alveolar epithelial barrier integrity is not well understood. Our aim is to determine whether PM exposure affects the alveolar epithelial cells (AEC) transepithelial
X Hua et al.
Placenta, 30(9), 780-784 (2009-07-31)
To evaluate the effects of contrast-enhanced ultrasound (CEU) on the permeability of placental barrier primarily. A total of 60 pregnant Sprague Dawley (SD) rats were divided into 10 groups, including six groups of microbubbles-enhanced ultrasound (varied mechanical index (MI) of

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