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214353

碳酸钙负载钯

greener alternative

extent of labeling: 5 wt. % loading, unreduced, solid

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关于此项目

线性分子式:
Pd
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
24852830
NACRES:
NA.22
MDL number:
MFCD03427452
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产品名称

碳酸钙负载钯, extent of labeling: 5 wt. % loading, unreduced

Quality Level

100

form

solid

autoignition temp.

>1120 °F

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

extent of labeling

5 wt. % loading

greener alternative category

Enabling,

SMILES string

[Ca++].[Pd++].[O-]C([O-])=O.[O-]C([O-])=O

InChI

1S/2CH2O3.Ca.Pd/c2*2-1(3)4;;/h2*(H2,2,3,4);;/q;;2*+2/p-4

InChI key

XGLHAVVVUOEGIO-UHFFFAOYSA-J

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Palladium on calcium carbonate (Pd/CaCO3) can be used as a green catalyst for a variety of applications such as:
  • formation of an efficient catalytic system for Heck coupling reaction and hydroarylation reaction
  • synthesis of Lindlar catalyst for selective hydrogenation of alkynes
  • a catalytic reservoir in Miyaura-Suzuki cross-coupling reactions
  • Stille cross-coupling reactions

用于催化：
  • 含水 Heck 偶联和氢芳基化
  • 还原反应
  • 氢化反应

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pictograms

Flame
GHS02

signalword

Danger

hcodes

H228

Hazard Classifications

Flam. Sol. 1

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBR2044V
06219PH
07402TV
07120AR
05322PI

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Chun Wong Aaron Chan et al.
Nature communications, 5, 5787-5787 (2014-12-20)
Lindlar catalysts comprising of palladium/calcium carbonate modified with lead acetate and quinoline are widely employed industrially for the partial hydrogenation of alkynes. However, their use is restricted, particularly for food, cosmetic and drug manufacture, due to the extremely toxic nature

全球贸易项目编号

货号GTIN
214353-10G04061833540527
214353-50G04061833545249