225916
苄基氯化镁 溶液
2.0 M in THF
别名:
(Phenylmethyl)magnesium chloride, Benzylchloromagnesium, Chloro(phenylmethyl)magnesium
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关于此项目
线性分子式:
C6H5CH2MgCl
化学文摘社编号:
分子量:
150.89
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
878506
Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
2.0 M in THF
density
1.031 g/mL at 25 °C
functional group
phenyl
SMILES string
Cl[Mg]Cc1ccccc1
InChI
1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
InChI key
NRAFPLGJPPJUNB-UHFFFAOYSA-M
General description
氯苄镁是一种有机金属化合物，可用作Lewis酸和强碱。
Application
苄基氯化镁（格利雅试剂）可用作烷基化试剂：
- 烷基化喹啉基功能化Cp−铬(III)复合物，以作为前体用于制备活性烯烃聚合催化剂。
- 合成2,3-二取代苯并吡喃-4-酮、6-氯代-8- 甲基嘌呤衍生物和苯基丙氨酸衍生物。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Quinolyl-functionalised Cp-chromium polymerisation catalysts: synthesis and crystal structures of alkylation products
Enders M, et al.
Journal of Organometallic Chemistry, 687(1), 125-130 (2003)
A novel synthesis of 2, 3-disubstituted benzopyran-4-ones and application to the solid phase
Harikrishnan LS and Showalter HD H
Tetrahedron, 56(4), 515-519 (2000)
A facile three-step synthesis of 1, 2-amino alcohols using the Ellman homochiral tert-butylsulfinamide
Barrow JC, et al.
Tetrahedron Letters, 42(11), 2051-2054 (2001)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 225916-800ML | 04061837796586 |
| 225916-100ML | 04061838779915 |
| 225916-PZ | 04061823820226 |