289426
4,4′-联吡啶
98%
别名:
4,4′-联吡啶, 4,4′-无水联吡啶
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关于此项目
经验公式（希尔记法）:
C10H8N2
化学文摘社编号:
分子量:
156.18
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
209-036-3
Beilstein/REAXYS Number:
113176
MDL number:
Quality Level
assay
98%
form
powder
bp
305 °C (lit.)
mp
109-112 °C (lit.)
SMILES string
c1cc(ccn1)-c2ccncc2
InChI
1S/C10H8N2/c1-5-11-6-2-9(1)10-3-7-12-8-4-10/h1-8H
InChI key
MWVTWFVJZLCBMC-UHFFFAOYSA-N
General description
4,4′-bpy通常用于桥接金属中心以形成具有新特性的配位聚合物。4,4′-bpy配体可通过稳定磁序来介导顺磁性金属离子之间的电子效应。
4,4′-联吡啶(BPY)是一种主要用于制备配位聚合物的有机交联剂。它是一种吡啶衍生物，其中的吡啶基可以沿着碳碳结构旋转。它可以作为光电化学还原的催化剂。
Application
4,4′-联吡啶(4,4′-联吡啶,4,4′-bpy)和Co(NCS)2 溶液相互扩散形成单晶Co(NCS)2(4,4′-bipy)2·2(CH3CH2)2O和Co(NCS)2(4,4′-bipy)2·2(CH3CH2)2O。
BPY是一种配体，在过渡金属之间形成网络，从而形成配位键。可通过配位聚合物和BPY作为复合连接剂制备杂化纳米片。它由两个活性位点组成，可用于药物开发。
signalword
Danger
hcodes
pcodes
Hazard Classifications
Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
商品
Graphene is the building block for carbon nanomaterials with different dimensionalities.
Bottom-up approach for the preparation of hybrid nanosheets based on coordination polymers made of metal-diethyloxaloacetate complexes linked by 4, 4′-bipyridine.
Portoles-Gil N, et al.
CrystEngComm, 19(34), 4972-4982 (2017)
Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4`-Bipyridine:? Syntheses and Structures
Lu J, et al.
Inorganic Chemistry, 36 (5), 923-929 null
Investigation of supramolecular interaction in 4, 4′-bipyridine crystal by hydrostatic pressure spectroscopies.
Li A, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 202(40), 70-75 (2018)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 289426-25G | 04061826284278 |
| 289426-5G | 04061826284285 |