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335312

2-戊炔-1-醇

Name: 2-戊炔-1-醇
Brand: ALDRICH

98%

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关于此项目

线性分子式:

C₂H₅C≡CCH₂OH

化学文摘社编号:

6261-22-9

分子量:

84.12

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24860304

EC Number:

228-411-2

Beilstein/REAXYS Number:

1734007

MDL number:

MFCD00040915

Assay:

98%

Form:

liquid

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属性

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.452 (lit.)

bp

84-85 °C/57 mmHg (lit.)

density

0.909 g/mL at 25 °C (lit.)

SMILES string

CCC#CCO

InChI

1S/C5H8O/c1-2-3-4-5-6/h6H,2,5H2,1H3

InChI key

WLPYSOCRPHTIDZ-UHFFFAOYSA-N

说明

Application

2-Pentyn-1-ol was employed as starting reagent for the synthesis of (-)-muricatacin. It was also used in the preparation of (2Z)-3-tributylstannyl-2-penten-1-ol.

pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H315,H319,H335

pcodes

P210 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

136.4 °F - closed cup

flash_point_c

58 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Synthesis of 9Z-9-substituted retinoic acids by palladium catalyzed coupling reaction of a vinyl triflate with alkenyl stannanes.

A Wada et al.

Chemical & pharmaceutical bulletin, 48(9), 1391-1394 (2000-09-19)

Palladium catalyzed cross coupling reactions of a vinyl triflate intermediate and various alkenyl stannanes afforded trisubstituted Z-olefins stereoselectively in high yields. These olefins were then converted to the corresponding 9Z-retinoic acids via Horner-Emmons reaction and subsequent basic hydrolysis in excellent

Synthesis of (-)-muricatacin.

H Makabe et al.

Bioscience, biotechnology, and biochemistry, 57(6), 1028-1029 (1993-06-01)

The synthesis of (-)-muricatacin starting from 1-bromododecane and 2-pentyn-1-ol is described. 2-Pentadecyn-1-ol (4), which was prepared from 1-bromododecane (2) and 2-pentyn-1-ol (3), was converted to epoxy alcohol 6 through a two-step reaction sequence, 6 being successively submitted to tosylation, iodination

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货号	GTIN
335312-5G	04061838090362