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文件

379840

Sigma-Aldrich

氯化铂(IV)

≥99.99% trace metals basis

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别名:
四氯化铂
线性分子式:
PtCl4
CAS号:
13454-96-1
分子量:
336.89
EC 号:
236-645-1
MDL编号:
MFCD00011182
PubChem化学物质编号:
24863693
NACRES:
NA.23

检测方案

≥99.99% trace metals basis

形式

powder and chunks

reaction suitability

reagent type: catalyst
core: platinum

杂质

≤100.0 ppm Trace Metal Analysis

mp

370 °C (dec.) (lit.)

密度

4.303 g/mL at 25 °C (lit.)

SMILES string

Cl[Pt](Cl)(Cl)Cl

InChI

1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4

InChI key

FBEIPJNQGITEBL-UHFFFAOYSA-J

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相关类别

一般描述

Platinum (IV)chloride is a highly oxidizing crystalline compound that can easily undergo reduction-oxidation reactions. It is widely used to synthesize Pt-based nanomaterials and catalysts.

应用

Platinum (IV) chloride can be used:
  • As a precursor to synthesize Pt nanoparticles for photocatalytic hydrogen generation.
  • As a starting material to prepare Pt/Al2O3 and Pt/ZrO2-SiO2 catalysts.
  • To fabricate an electrocatalyst for proton exchange fuel cells.
  • As a catalyst for the cyclization of arene−alkynesubstrates via intramolecular electrophilic hydroarylation.

警示用语：

Danger

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

储存分类代码

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Lu Zhao et al.
Zhejiang da xue xue bao. Yi xue ban = Journal of Zhejiang University. Medical sciences, 38(1), 59-66 (2009-03-03)
To construct a drug carrier and gene vector PEG-PEI-Pt. Polyethyleneglycol (PEG) was coupled to polyethylenimine (PEI 600) and platinum tetrachloride; PEG-PEI-Pt complex was formed in ethanol. The complex was characterized by XRD, UV-VIS and FT-IR and the DNA condensation was
N Kanematsu et al.
Gifu Shika Gakkai zasshi = The Journal of Gifu Dental Society, 17(2), 575-581 (1990-12-01)
The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (HGPRT) locus in V-79 cells. Cadmium chloride at a concentration of 0.05 microM induced ford mutation in V-79
A M Reichlmayr-Lais et al.
Journal of trace elements and electrolytes in health and disease, 6(3), 183-187 (1992-09-01)
In experiments with rats dose-response relationships of alimentary PtCl2 and PtCl4 were investigated. 2 x 81 animals weighing 35 g were randomly distributed among 9 treatment groups which were fed ad libitum with a synthetic diet containing various amounts of
Eric Ennifar et al.
Nucleic acids research, 31(10), 2671-2682 (2003-05-09)
Metal ions, and magnesium in particular, are known to be involved in RNA folding by stabilizing secondary and tertiary structures, and, as cofactors, in RNA enzymatic activity. We have conducted a systematic crystallographic analysis of cation binding to the duplex
B A Teicher et al.
Anticancer research, 13(5A), 1549-1556 (1993-09-01)
Since several anticancer drugs are known to become more cytotoxic to cells in an acidic milieu, we have attempted to utilize the carbonic anhydrase inhibitor, Acetazolamide, to acidify the blood and tumor of C3H mice bearing the FSaIIC fibrosarcoma in
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