422878
甲醇-d4
99 atom % D
别名:
全氘代甲醇, 四氘代甲醇
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关于此项目
线性分子式:
CD3OD
化学文摘社编号:
分子量:
36.07
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
EC Number:
212-378-6
Beilstein/REAXYS Number:
1733278
MDL number:
Isotopic purity:
99 atom % D
Assay:
99% (CP)
Form:
liquid
isotopic purity
99 atom % D
Quality Level
assay
99% (CP)
form
liquid
expl. lim.
5.5-36.5 % (lit.)
technique(s)
NMR: suitable
impurities
≤0.025% water
water
refractive index
n20/D 1.326 (lit.)
bp
65.4 °C (lit.)
mp
-99 °C (lit.)
density
0.888 g/mL at 25 °C (lit.)
format
neat
SMILES string
[2H]OC([2H])([2H])[2H]
InChI
1S/CH4O/c1-2/h2H,1H3/i1D3,2D
InChI key
OKKJLVBELUTLKV-MZCSYVLQSA-N
General description
Methanol-d4 (CD3OD) is a deuterated NMR solvent. It is useful in NMR-based research and analyses. Absolute infrared absorption intensities of CD3OD have been reported between 8000 and 350cm-1.1
Application
Methanol-d4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.
Other Notes
Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.
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Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
target_organs
Eyes,Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
49.5 °F - closed cup
flash_point_c
9.7 °C - closed cup
法规信息
危险化学品
此项目有
相关内容
Infrared intensities of liquids. XVII. Infrared refractive indices from 8000 to 350 cm-1, absolute integrated absorption intensities, transition moments, and dipole moment derivatives of methan-d3-ol and methanol-d4 at 25?C.
Bertie JE and Zhang SL.
J. Chem. Phys., 101(10), 8364-8379 (1994)
The Rates of Methoxyl Exchange of Camphor and Norcamphor Dimethyl Ketals in Methanol-d4.
Traylor TG and Perrin CL.
Journal of the American Chemical Society, 88(21), 4934-4942 (1966)
Cheng-Kun Lin et al.
Organic & biomolecular chemistry, 13(7), 2100-2107 (2014-12-20)
A straightforward synthesis of novel, 2-heterocyclyl polyhydroxylated pyrrolidines is described. Stereocontrolled additions of nucleophiles to cyclic nitrones generated the corresponding 2,3-trans adducts, allowing the synthesis of the corresponding pyrrolidines via key intermediates bearing an alkyne and a nitrile oxide. Three
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 422878-10ML | 04061832103259 |
| 422878-50ML | 04061832103266 |