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661384

2-碘酰基苯甲酸

Name: 2-碘酰基苯甲酸
Brand: ALDRICH

contains stabilizer, 45 wt. % (IBX)

别名:

2-碘酰苯甲酸, SIBX

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关于此项目

经验公式（希尔记法）:

C₇H₅IO₄

化学文摘社编号:

61717-82-6

分子量:

280.02

NACRES:

NA.22

PubChem Substance ID:

24884529

UNSPSC Code:

12352005

MDL number:

MFCD02912492

Form:

solid

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属性

form

solid

Quality Level

100

contains

stabilizer

reaction suitability

reagent type: oxidant

concentration

45 wt. % (IBX)

functional group

iodo

SMILES string

OI1(=O)OC(=O)c2ccccc12

InChI

1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)

InChI key

CQMJEZQEVXQEJB-UHFFFAOYSA-N

说明

Application

用于在 DMSO 存在的条件下将芴甲氧羰基保护的氨基醇氧化为相应的氨基醛的试剂。

稳定的2-碘氧基苯甲酸

是 IBX 的稳定形态 (SIBX)，不具有 IBX 的任何易爆性，同时保持了出色的反应性和选择性。

Other Notes

本品在苯甲酸和间苯二甲酸中稳定。

pictograms

GHS08,GHS05,GHS07

signalword

Danger

hcodes

H314,H335,H372

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Lungs, Respiratory system

supp_hazards

EUH044

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

pcodes

P260 - P271 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P314

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A stabilized formulation of IBX (SIBX) for safe oxidation reactions including a new oxidative demethylation of phenolic methyl aryl ethers.

Aurélie Ozanne et al.

Organic letters, 5(16), 2903-2906 (2003-08-02)

[reaction: see text] SIBX is a nonexplosive formulation of IBX that can be used as a suspension in a variety of standard organic solvents such as refluxing EtOAc and THF to oxidize safely alcohols into aldehydes and ketones. The use

Lipophilization of Hydroxytyrosol-Enriched Fractions from Olea europaea L. Byproducts and Evaluation of the in Vitro Effects on a Model of Colorectal Cancer Cells.

Roberta Bernini et al.

Journal of agricultural and food chemistry, 65(31), 6506-6512 (2017-03-14)

A hydroxytyrosol (HTyr)-enriched fraction containing HTyr 6% w/w, derived from Olea europaea L. byproducts and obtained using an environmentally and economically sustainable technology, was lipophilized under green chemistry conditions. The effects of three fractions containing hydroxytyrosyl butanoate, octanoate, and oleate

Synthetic Communications, 37, 3493-3493 (2007)

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全球贸易项目编号

货号	GTIN
CDS019650-100MG	04061828951345
661384-50G	04061832734101
661384-10G	04061832734088
661384-1G	04061832734095
661384-250G	04061833399484