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Merck
CN

674435

16-巯基十六碳酸

98%

别名:

MHDA

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关于此项目

线性分子式:
HS(CH2)15CO2H
化学文摘社编号:
分子量:
288.49
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Assay:
98%
Form:
solid
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Quality Level

assay

98%

form

solid

mp

65-69 °C

storage temp.

2-8°C

SMILES string

OC(=O)CCCCCCCCCCCCCCCS

InChI

1S/C16H32O2S/c17-16(18)14-12-10-8-6-4-2-1-3-5-7-9-11-13-15-19/h19H,1-15H2,(H,17,18)

InChI key

INOAASCWQMFJQA-UHFFFAOYSA-N

General description

16-巯基十六烷酸(MHA)是一种具有长链 −CH2 基团的链烷硫醇,可在多种基材上形成自组装单层膜(SAM)。

Application

与含氟NNN′,N′-四甲基氟膦酰胺一起在自组装单分子膜上形成链间羧酸酐。该化合物可用于通过自组装产生亲水性SAM。所获得的单层膜可通过羧酸封端与各种胺和醇一起进行进一步官能化,从而引入更复杂的端基或多层膜。
MHA可通过笔式光刻(PPL)在金表面上形成SAM。它可用于生物工程应用中。它也可以用于对金双棱锥体进行功能化,从而可以制造用于壳分离的纳米粒子增强拉曼光谱仪(SHINERS)的纳米谐振器。


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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Self-assembled monolayers (SAMs) have diverse applications; article compares benefits of alkylthiolates on gold SAM systems.

Recent research highlights tunable properties of inorganic nanoparticles, driving interest in optoelectronics.


Guusje Delen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(1), 187-195 (2017-11-23)
Control over assembly, orientation, and defect-free growth of metal-organic framework (MOF) films is crucial for their future applications. A layer-by-layer approach is considered a suitable method to synthesize highly oriented films of numerous MOF topologies, but the initial stages of
Chuanzhen Zhou et al.
Langmuir : the ACS journal of surfaces and colloids, 26(11), 8441-8449 (2010-04-21)
Ultrathin complex multilayer structures have many potential applications in molecular and organic electronics, sensing, biotechnology and other areas. Reported here is a method by which to construct multifunctional, multilayer, patterned structures, using alkanethiolate SAMs adsorbed on Au, UV photopatterning, and
Young Shik Chi et al.
Langmuir : the ACS journal of surfaces and colloids, 22(16), 6956-6960 (2006-07-26)
In this paper, we report the reactivity of fluoro-N,N,N',N'-tetramethylformamidinium hexafluorophosphate (TFFH), a reagent for transformation of carboxylic acids into acid fluorides in solution, toward self-assembled monolayers (SAMs) of 16-mercaptohexadecanoic acid on gold. Contrary to the solution-based reactions, we found that



全球贸易项目编号

货号GTIN
674435-250MG04061832735658