B57400
4-溴苯甲醛
ReagentPlus®, 99%
别名:
1-溴-4-甲酰苯, 4-溴苯甲醛, 4-甲酰基-1-溴苯, 4-甲酰基苯基溴, 4-甲酰溴苯, 对溴苯甲醛, 对甲酰基溴苯
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关于此项目
线性分子式:
BrC6H4CHO
化学文摘社编号:
分子量:
185.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-365-0
Beilstein/REAXYS Number:
507100
MDL number:
Assay:
99%
Form:
crystals
Quality Level
product line
ReagentPlus®
assay
99%
form
crystals
mp
55-58 °C (lit.)
SMILES string
[H]C(=O)c1ccc(Br)cc1
InChI
1S/C7H5BrO/c8-7-3-1-6(5-9)2-4-7/h1-5H
InChI key
ZRYZBQLXDKPBDU-UHFFFAOYSA-N
Application
4-溴苯甲醛可用作反应剂：
- 在三苯基膦催化剂存在下，与端炔酸酯类反应合成乙烯酯类。
- 与苯乙烯通过钯催化的Mizoroki-Heck交联反应合成芳基化烯烃。
- 与甲酰基苯硼酸类通过Suzuki-Wittig反应合成二甲基二苯基二丙烯酸酯类。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
228.2 °F - closed cup
flash_point_c
109 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
商品
Effective in key synthesis reactions like Knoevenagel condensation, thalidomide synthesis, and Suzuki coupling for sustainable chemical transformations.
Tetrahedron Letters, 48, 539-539 (2007)
Gary A Molander et al.
The Journal of organic chemistry, 71(26), 9681-9686 (2006-12-16)
We have previously reported that the palladium-catalyzed cross-coupling reaction of potassium vinyltrifluoroborate with aryl electrophiles proceeds with good yields. Herein, we describe recent progress in optimizing the reaction, as well as outlining the scope and limitations of the reaction. The
Timo Rhauderwiek et al.
Chemical science, 9(24), 5467-5478 (2018-07-17)
The Ni-metallated porphyrin-based tetraphosphonic acid (Ni-tetra(4-phosphonophenyl)porphyrin, Ni-H8TPPP) was used for the synthesis of highly porous metal phosphonates containing the tetravalent cations Zr4+ and Hf4+. The compounds were thoroughly characterized regarding their sorption properties towards N2 and H2O as well as
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| B57400-100G | 04061833434109 |
| B57400-25G | 04061833434123 |
| B57400-10G | 04061833434116 |