82270
1,2-二氯丙烷
99%
别名:
二氯化丙烯
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关于此项目
线性分子式:
CH3CHClCH2Cl
化学文摘社编号:
分子量:
112.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-152-2
Beilstein/REAXYS Number:
1718880
MDL number:
Assay:
99%
Form:
liquid
vapor density
3.89 (vs air)
Quality Level
vapor pressure
40 mmHg ( 19.4 °C)
assay
99%
form
liquid
autoignition temp.
1035 °F
expl. lim.
14.5 %
refractive index
n20/D 1.439
bp
95-96 °C (lit.)
mp
−100 °C (lit.)
density
1.156 g/mL at 25 °C (lit.)
functional group
chloro
SMILES string
CC(Cl)CCl
InChI
1S/C3H6Cl2/c1-3(5)2-4/h3H,2H2,1H3
InChI key
KNKRKFALVUDBJE-UHFFFAOYSA-N
General description
1,2-二氯丙烷，又称为二氯化丙烯，是一种氯化溶剂，常作为中间体合成基础有机化合物。
Application
1,2-二氯丙烷可用作合成以下物质的结构单元：
- 在乙磺酸钠的参与下，与二硫化碳和活性亚甲基化合物通过一锅反应合成的2-烯基-1,3-二噻茂烷衍生物。
- β与硫醇的可控脱氯偶联反应制备的氯丙基硫化合物。
- 在磷叶立德催化的条件下，与 β-酮基硫代酰胺通过[3+2]和[3+3]环化反应制备的噻唑烷和1，3-噻嗪烷衍生物。
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
59.0 °F - closed cup
flash_point_c
15.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of some 2-ylidene-1, 3-dithiolanes
Lipin KV, et al.
Russ. J. Org. Chem., 53(1), 147-149 (2017)
H D Kirk et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 28(1), 18-26 (1995-11-01)
1,2-Dichloropropane (PDC) was evaluated for its potential to cause embryonal/fetal toxicity and teratogenicity in pregnant rats and rabbits. PDC was administered via oral gavage at dose levels of 0, 10, 30, or 125 mg/kg/day on Days 6 through 15 of
A Odinecs et al.
Renal failure, 17(5), 517-524 (1995-09-01)
The contribution of testosterone to the nephrotoxic effects of 1,2-dichloropropane (DCP) was assessed by a series of castration and sex hormone replacement experiments on Wistar rats. The nephrotoxic action of DCP was evaluated by measuring the accumulation of organic anion