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CN222380

氯化烯丙基钯(II)二聚体

别名:

\ [氯化钯(C3H5)] 2

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关于此项目

经验公式(希尔记法):
C6H10Cl2Pd2
化学文摘社编号:
分子量:
365.89
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
Beilstein/REAXYS Number:
4124623
MDL number:
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Quality Level

reaction suitability

reagent type: catalyst
core: palladium
reaction type: C-H Activation, reagent type: catalyst
core: palladium
reaction type: Cross Couplings

SMILES string

Cl[Pd]CC=C.Cl[Pd]CC=C

InChI

1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2

InChI key

TWKVUTXHANJYGH-UHFFFAOYSA-L

General description

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.[] We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Features and Benefits

Application Guide for Palladium Catalyzed Cross-Coupling Reactions Allylpalladium(II) chloride dimer has been employed for the following studies: Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.[] Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.[] Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.[] As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M. On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors


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Warning

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Hazard Classifications

Skin Irrit. 2

存储类别

11 - Combustible Solids



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全球贸易项目编号

货号GTIN
CN222380-1G04065273478631
CN222380-5G04065273478648