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Merck
CN

129046

2,2,2-Trifluoroethylhydrazine solution

70 wt. % in H2O

Synonym(s):

Trifluoroethylhydrazine

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About This Item

Linear Formula:
CF3CH2NHNH2
CAS Number:
Molecular Weight:
114.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Form:
liquid
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form

liquid

Quality Level

concentration

70 wt. % in H2O

refractive index

n20/D 1.361

transition temp

flash point 62 °C

density

1.294 g/mL at 25 °C

functional group

amine, fluoro, hydrazine

SMILES string

NNCC(F)(F)F

InChI

1S/C2H5F3N2/c3-2(4,5)1-7-6/h7H,1,6H2

InChI key

OPMFFAOEPFATTG-UHFFFAOYSA-N

Application

Building block for fluorinated pyridazines and fluoroalkyl hydrazones of β-phosphonates.
2,2,2-trifluoroethylhydrazine was added to myoglobin to study its interaction with heme protein. It was also used to determine aldehydes and acetone simultaneously in water.


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

143.6 °F

flash_point_c

62 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Journal of Fluorine Chemistry, 121, 177-177 (2003)
Y S Choe et al.
The Journal of biological chemistry, 266(13), 8523-8530 (1991-05-05)
The oxidative reaction of equine myoglobin with alkylhydrazines results primarily in introduction of the alkyl group at the sterically hindered gamma-meso position. The gamma-meso adducts formed with ethyl- and n-butylhydrazine have been isolated and unambiguously identified. With high pressure liquid
Synthetic Communications, 36, 2719-2719 (2006)



Global Trade Item Number

SKUGTIN
129046-25G04061836825126
129046-5G04061838726063