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Sigma-Aldrich

Ruthenium(III) chloride hydrate

ReagentPlus®

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Synonym(s):
Ruthenium trichloride
Linear Formula:
RuCl3 · xH2O
CAS Number:
14898-67-0
Molecular Weight:
207.43 (anhydrous basis)
EC Number:
233-167-5
MDL number:
MFCD00149844
PubChem Substance ID:
24852386
NACRES:
NA.23

product line

ReagentPlus®

form

powder and chunks

composition

Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%

reaction suitability

reagent type: catalyst
core: ruthenium

impurities

≤0.1% Insoluble matter (C=1%, 25% HCl)

SMILES string

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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General description

soluble form

Application

It is used to prepare a nanoparticulate ruthenium-aluminum oxyhydroxide catalyst for the efficient dehydrogenation arylmethyl alcohols to the corresponding aldehydes. The product catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine. Ruthenium hydrated oxide, prepared from RhCl3 when deposited on titania nanotubes can be used as a catalyt system for selective oxidation of alcohols by oxygen.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

H302 - H314 - H411

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Xingcui Guo et al.
Scientific reports, 5, 16451-16451 (2015-11-19)
Ruthenium (Ru) supported on activated carbon (AC) and carbon nanotubes (CNTs) was carried out in the hydrogenolysis of sorbitol to ethylene glycol (EG) and 1,2-propanediol (1,2-PD) under the promotion of tungsten (WOx) species and different bases. Their catalytic activities and
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