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262145

Perfluorohexyl iodide

Name: Perfluorohexyl iodide
Brand: ALDRICH

99%

Synonym(s):

Tridecafluoro-1-iodohexane, 1-Iodoperfluorohexane, 1-Iodotridecafluorohexane, Tridecafluorohexyl iodide

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About This Item

Linear Formula:

CF₃(CF₂)₅I

CAS Number:

355-43-1

Molecular Weight:

445.95

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24855861

EC Number:

206-586-6

Beilstein/REAXYS Number:

1802118

MDL number:

MFCD00001063

Assay:

99%

Form:

liquid

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Properties

Quality Level

100

assay

99%

form

liquid

refractive index

n20/D 1.329 (lit.)

bp

117 °C (lit.)

density

2.063 g/mL at 25 °C (lit.)

functional group

fluoro, iodo

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)I

InChI

1S/C6F13I/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI key

BULLJMKUVKYZDJ-UHFFFAOYSA-N

Description

General description

Perfluorohexyl iodide forms 1:1 complexes with a variety of hydrogen-bond acceptors. It has been grafted onto the isocitronellene/propene copolymer by radical reaction yielding a poly(α-olefin) with fluorinated side chains. The radical addition of perfluorohexyl iodide to vinyl acetate, using azo-bis( isobutyronitrile) (AIBN) as an initiator, has been investigated.

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

239.0 °F - closed cup

flash_point_c

115 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Broadband

Alexander A Marchione et al.

Journal of magnetic resonance (San Diego, Calif. : 1997), 286, 143-147 (2017-12-16)

A train of BURBOP universal rotation pulses has been used to generate a spin lock sufficient to observe TOCSY correlations over a 46 kHz

Zirconocene-MAO-catalyzed homo-and copolymerizations of linear asymmetrically substituted dienes with propene: A novel strategy to functional (co) poly (a-olefin) s.

Hackmann M, et al.

Macromolecular Chemistry and Physics, 199(8), 1511-1517 (1998)

Non-covalent interactions between iodo-perfluorocarbons and hydrogen bond acceptors.

Rafel Cabot et al.

Chemical communications (Cambridge, England), (15)(15), 2005-2007 (2009-04-01)

Quantitative studies of the 1 : 1 complexes formed between perfluorohexyl iodide and a variety of hydrogen-bond acceptors have been used to probe the relationship between halogen bonding, hydrogen bonding, desolvation and the electrostatics of non-covalent interactions.

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Global Trade Item Number

SKU	GTIN
262145-25G	04061838348142
262145-5G	04061837595394