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345105

Ethylmagnesium bromide solution

1.0 M in tert-butyl methyl ether

Synonym(s):

Bromoethylmagnesium

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About This Item

Linear Formula:
CH3CH2MgBr
CAS Number:
925-90-6
Molecular Weight:
133.27
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24861294
MDL number:
MFCD00000043
Beilstein/REAXYS Number:
3587203
Concentration:
1.0 M in tert-butyl methyl ether
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Quality Level

100

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal™ of

concentration

1.0 M in tert-butyl methyl ether

density

0.841 g/mL at 25 °C

SMILES string

CC[Mg]Br

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

InChI key

TWTWFMUQSOFTRN-UHFFFAOYSA-M

Application


  • Solution Structure and Magnesium Deposition Electrochemistry of Mixing Alkylmagnesium Halide with Magnesium Sulfonyl Amide/Glyme Solution: This research explores the electrochemical behavior of ethylmagnesium bromide in mixed solutions for magnesium deposition applications (Egashira & Hiratsuka, 2016).

  • Ethyl magnesium bromide as an efficient anionic initiator for controlled polymerization of ε-caprolactone: The article investigates the use of ethylmagnesium bromide as an initiator for the controlled polymerization of ε-caprolactone (Malinová & Brožek, 2014).

  • Room temperature electrodeposition of metallic magnesium from ethylmagnesium bromide in tetrahydrofuran and ionic liquid mixtures: This research focuses on the electrodeposition of metallic magnesium using ethylmagnesium bromide in various solvent mixtures (Chen et al., 2015).

Legal Information

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pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

-29.2 °F - closed cup

flash_point_c

-34 °C - closed cup

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react. 1

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBJ4731
SHBH0047V
SHBG9055V
SHBB0193
S44016

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M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
R G Xie et al.
Steroids, 55(11), 488-490 (1990-11-01)
The reaction of ethyl magnesium bromide and 17 alpha-ethynylestradiol with formaldehyde in the presence of triethyl phosphate or hexamethylphosphoramide gave the 2- and 4-formyl-17 alpha-ethynylestradiol in high yield. Treatment of the formyl derivatives with an alkaline solution of hydrogen peroxide
T Nishiyama et al.
Chemical & pharmaceutical bulletin, 48(12), 1999-2002 (2001-01-06)
The direct alpha-bromination of various ketones using trifluoromethanesulfonic anhydride and Grignard reagent or magnesium bromide in ether gave the corresponding alpha-bromo ketones in moderate to good yields under mild reaction conditions.
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Global Trade Item Number

SKUGTIN
345105-100ML04061826759134
345105-800ML04061837797217