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Sigma-Aldrich

Bis(ethylenediamine)copper(II) hydroxide solution

1.0 M in H2O

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Synonym(s):
Copper(II)-ethylenediame complex
Linear Formula:
Cu(H2NCH2CH2NH2)2(OH)2
CAS Number:
14552-35-3
Molecular Weight:
217.76
MDL number:
MFCD00274628
PubChem Substance ID:
24867790
NACRES:
NA.23

form

liquid

reaction suitability

reagent type: catalyst
core: copper

concentration

1.0 M in H2O

density

1.086 g/mL at 25 °C

SMILES string

O[Cu]O.NCCN.NCCN

InChI

1S/2C2H8N2.Cu.2H2O/c2*3-1-2-4;;;/h2*1-4H2;;2*1H2/q;;+2;;/p-2

InChI key

WATCRQGYOIZIHC-UHFFFAOYSA-L

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General description

Bis(ethylenediamine)copper(II) hydroxide solution is a stable complex formed by copper (Cu) ions with ethylenediamine. It is a transition metal solution that can be used as a catalyst for electrochemical reduction process.

Application

Bis(ethylenediamine)copper(II) hydroxide has been used to evaluate cation exchange capacity (CEC) of clays by copper absorption.
Copper(II) ethylenediamine complex may be used to evaluate the cation exchange capacity (CEC) of clay materials. It may also be used to modify polyoxoniobate, which is a class of polyoxometalates (POMs) that finds potential application in photocatalytic H2 production.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Far-infrared and electronic spectra of some bis (ethylenediamine) and related complexes of copper (II) and the relevance of these data to tetragonal distortion and bond strengths.
Lever ABP and Mantovani E
Inorganic Chemistry, 10(4), 817-826 (1971)
A copper (ii)-ethylenediamine modified polyoxoniobate with photocatalytic H2 evolution activity under visible light irradiation.
Wang Z, et al.
Dalton Transactions, 41(33), 9882-9884 (2012)
CEC of clays: measurement by adsorption of a copper ethylenediamine complex
Bergaya F and Vayer M
Applied Clay Science, 12(3), 275-280 (1997)
Determination of the cation exchange capacity (CEC) of clay minerals using the complexes of copper (II) ion with triethylenetetramine and tetraethylenepentamine.
Lorenz P, et al.
Clays and Clay Minerals, 47, 386-388 (1999)

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