450782
Chromium(II) chloride
powder, 99.99% trace metals basis
Synonym(s):
Chromium dichloride, Chromous chloride
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About This Item
Linear Formula:
CrCl2
CAS Number:
Molecular Weight:
122.90
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-163-3
MDL number:
Assay:
99.99% trace metals basis
Grade:
anhydrous
Form:
powder
grade
anhydrous
Quality Level
assay
99.99% trace metals basis
form
powder
reaction suitability
core: chromium
impurities
≤150.0 ppm Trace Metal Analysis
mp
824 °C (lit.)
density
2.9 g/mL at 25 °C (lit.)
SMILES string
Cl[Cr]Cl
InChI
1S/2ClH.Cr/h2*1H;/q;;+2/p-2
InChI key
XBWRJSSJWDOUSJ-UHFFFAOYSA-L
Application
Mediates the condensation of the aldehydes with trisubstituted chloroalkenes. Used in the synthesis of a highly active precatalyst for ethylene oligimerization.
Used to make bis(indenyl)chromium dimer and related products.
Used with iodoform and tetraethyl ethylenediamine to convert terminal olefins into trans-iodocyclopropanes in excellent yields.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Heinemann, O. et al.
Organometallics, 15, 5462-5462 (1996)
Falck, J.R., et al.
Tetrahedron Letters, 45, 3039-3039 (2004)
Small, B.L., et al.
Macromolecules, 37, 4375-4375 (2004)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 450782-5G | 04061832323855 |
| 450782-1G | 04061838140081 |
| 450782-25G | 04061838140098 |