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649813

PEDOT

tetramethacrylate end-capped solution, 0.5 wt. % (dispersion in propylene carbonate), contains p-toluenesulfonate as dopant

Synonym(s):

Oligotron™ PC, PEDOT, PEDOT, tetramethacrylate end-capped

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About This Item

CAS Number:
126213-51-2
UNSPSC Code:
12352103
NACRES:
NA.23
EC Number:
203-572-1
MDL number:
MFCD06798809
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Product Name

Poly(3,4-ethylenedioxythiophene), tetramethacrylate end-capped solution, 0.5 wt. % (dispersion in propylene carbonate), contains p-toluenesulfonate as dopant

Quality Level

100

mol wt

~1,360-1,600 g/mol (methacrylate equivalent weight), average Mn ~6,000(lit.)

contains

p-toluenesulfonate as dopant

composition

Oligotron™ tetramethacrylate, 0.5 wt. % , propylene carbonate, 99.5 wt. %

concentration

0.5 wt. % (dispersion in propylene carbonate)

resistance

1-10 M Ω/sq (typical surface resistance of film)

conductivity

0.1-0.5 S/cm (bulk)

density

1.189 g/mL at 25 °C

General description

Please follow this link for Aedotron/Oligotron selection guide table.
Poly(3,4-ethylenedioxythiophene), tetramethacrylate end-capped solution (PEDOT-Meth) is a semiconductor based polymer that is functionalized with tetramethacrylate that facilitates effective crosslinking of the conjugated films.
The main characteristic of Oligotron™ PC is that it behaves as a reactive oligomer in non-volatile solvent. Used blended with monomers, or for reactions with functional compounds.

Application

PEDOT-Meth can be used as a plasticizing membrane in the fabrication of ion-selective sensors and light emitting diodes.
For best results, agitate for 20 minutes prior to use. Films cast from propylene carbonate will require heat to dry. Photocurable inks can be formulated by adding acrylate monomers and photoinitiators (i.e. DMPA). Propylene carbonate will remain in the polymer. Functional compounds can be coupled to the oligomer via reactions at the methacrylate group.
Product can be blended with additional acrylate or methacrylate monomers and crosslinked to make polymer blends. Custom molecules can be synthesized by bonding functional compounds, via the methacrylate groups, to the conducting EDOT oligomers.

Features and Benefits

End-capped structure renders the conducting oligomer PEDOT dispersible. The methacrylate groups offer the potential for crosslinking, or addtional chemical functionalization. Completely dried Oligotron(TM) tetramethacrylate via the methacrylate functional groups.

Legal Information

Oligotron is a trademark of TDA Research, Inc.

Disclaimer

Store this product at room temperature (do not refrigerate or freeze). Some settling will normally occur. Agitate, sonicate, and filter prior to use. A plug of glass wool in a pipette can be used for easy filtration. The shelf life of this product will vary depending on how it is stored and handled. Product should be discarded if heavy aggregation occurs, or if sonication / filtering are inadequate to produce a good casting solution.

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pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

269.6 °F - closed cup

flash_point_c

132 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
MKCG8740
MKCB8877
MKBV8987V
MKBP4342V
MKBG8313V

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Articles

Conducting Polymer Device Applications

The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

Conjugated Polymers for the Engineering of Device/Tissue Interface

Conjugated polymers offer charge transport between inorganic, electrically conducting metals and organic, proton-conducting biological systems.

Flexible and Printed Organic Thermoelectrics: Opportunities and Challenges

Progress in Organic Thermoelectric Materials & Devices including high ZT values of >0.2 at room temperature by p-type (PEDOT:PSS) & n-type (Poly[Kx(Ni-ett)]) materials are discussed.

Synthesis of water-free PEDOT with polyvinylpyrrolidone stabilizer in organic dispersant system
He J, et al.
Organic Electronics, 53, 117-126 (2018)
Composite Polyacrylate- Poly (3, 4-ethylenedioxythiophene) Membranes for Improved All-Solid-State Ion-Selective Sensors
Rzewuska A, et al.
Analytical Chemistry, 80(1), 321-327 (2008)
Cristina Ocaña et al.
Talanta, 186, 279-285 (2018-05-23)
We report here the fabrication of solid-contact calcium-selective electrodes (Ca2+-SCISEs) made of a polyurethane acrylate ion-selective membrane (ISM) that was covalently attached to the underlying ion-to-electron transducer (solid-contact). Methacrylate-functionalized poly(3,4-ethylenedioxythiophene) (Meth-PEDOT) and Meth-PEDOT films containing either multiwalled carbon nanotubes (MWCNT)

Global Trade Item Number

SKUGTIN
649813-25G04061833599839