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723169

Bis[2-(2′-bromoisobutyryloxy)ethyl]disulfide

Synonym(s):

(BiBOE)2S2, ATRP (Bio)degradable Initiator, BiBOEDS

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About This Item

Empirical Formula (Hill Notation):
C12H20Br2O4S2
CAS Number:
817637-79-9
Molecular Weight:
452.22
NACRES:
NA.23
PubChem Substance ID:
329763982
UNSPSC Code:
12162002
MDL number:
MFCD16621491
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form

liquid

Quality Level

100

refractive index

n20/D 1.529

density

1.478 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(Br)C(=O)OCCSSCCOC(=O)C(C)(C)Br

InChI

1S/C12H20Br2O4S2/c1-11(2,13)9(15)17-5-7-19-20-8-6-18-10(16)12(3,4)14/h5-8H2,1-4H3

InChI key

PXBWWYBXPGZCHC-UHFFFAOYSA-N

Application

Atom Transfer Radical Polymerisation (ATRP) initiator for the preparation of biodegradable polymers as well as polymers that adhere to gold surfaces. May also be used to introduce a temperature and light sensitive cleavable region into the polymer.
ATRP for Everyone: Ligands and Initiators for the Clean Synthesis of Functional Polymers

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCK1456
MKCF0225
MKBZ3776V
MKBK4208V
MKBF7296V

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Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Articles

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Tsarevsky, N.V.; Matyjaszewski, K.
Macromolecules, 35, 9009-9009 (2002)
Hao Zhao et al.
ACS nano, 13(6), 6647-6661 (2019-05-16)
Highly efficient nanoarchitectures are of great interest for achieving precise chemotherapy with minimized adverse side effects in cancer therapy. However, a major challenge remains in exploring a rational approach to synthesize spatiotemporally selective vehicles for precise cancer chemotherapy. Here, we
Wenjing Huang et al.
Theranostics, 9(13), 3825-3839 (2019-07-10)
Reversing multidrug resistance (MDR) remains a big challenge in cancer therapy. Combining the hyperthermia and chemotherapy is a promising strategy for efficient cancer treatment with MDR reversal. Gold nanocages (GNCs) are an ideal photothermal (PTT)-chemotherapy integration platform due to their

Global Trade Item Number

SKUGTIN
723169-1G04061826280553
723169-5G04061832978161