728551
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
≥97% (AT), lumps
Synonym(s):
Chloro[N2-[2-(dimethylamino-κN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-κN1,κN2]-nickel, Nickamine
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About This Item
Empirical Formula (Hill Notation):
C16H20ClN3Ni
CAS Number:
Molecular Weight:
348.50
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride, ≥97% (AT)
Quality Level
assay
≥97% (AT)
form
lumps
reaction suitability
core: nickel, reagent type: catalyst
SMILES string
CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
InChI
1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
InChI key
IRLHVNUEEKJBEL-UHFFFAOYSA-M
Application
Catalyst for:
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
- Alkyl-alkyl Kumada coupling of secondary alkyl halides
- Direct alkylation of heterocyclic C-H bonds
- Sonogashira coupling of nonactivated alkyl halides
- Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.