Bis(triphenylphosphine)palladium(II) dichloride

Name: Bis(triphenylphosphine)palladium(II) dichloride
Brand: ALDRICH

solid

Synonym(s):

Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride, PdCl₂(PPh₃)₂

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About This Item

Linear Formula:

[(C₆H₅)₃P]₂PdCl₂

CAS Number:

13965-03-2

Molecular Weight:

701.90

NACRES:

NA.22

PubChem Substance ID:

329765477

UNSPSC Code:

12161600

EC Number:

237-744-2

MDL number:

MFCD00009593

Beilstein/REAXYS Number:

4935975

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Properties

Product Name

Bis(triphenylphosphine)palladium(II) dichloride,

form

solid

Quality Level

100

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium, reagent type: ligand

functional group

phosphine

SMILES string

Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4

InChI

1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

YNHIGQDRGKUECZ-UHFFFAOYSA-L

Description

Application

Bis(triphenylphosphine)palladium(II) dichloride is generally used as a catalyst for the synthesis of conjugated polymers via Stille coupling. It is also applicable to other coupling reactions such as Suzuki-and Sonogashira-coupling reactions

Application Guide for Palladium Catalyzed Cross-Coupling Reactions