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Merck
CN

79558

Sodium phosphomolybdate hydrate

technical

Synonym(s):

Molybdophosphoric acid sodium salt, Phosphomolybdic acid sodium salt hydrate

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About This Item

Linear Formula:
Na3[P(Mo3O10)4] · xH2O
CAS Number:
Molecular Weight:
1891.20 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
EC Number:
215-206-8
MDL number:
Technical Service
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grade

technical

Quality Level

form

crystals

reaction suitability

core: molybdenum, reagent type: catalyst, reagent type: oxidant

mp

98 °C (dec.) (lit.)

density

2.83 g/mL at 25 °C (lit.)

SMILES string

O.[Na+].[Na+].[Na+].[O-][Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)OP(=O)(O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo]([O-])(=O)=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo]([O-])(=O)=O

InChI

1S/12Mo.3Na.H3O4P.H2O.36O/c;;;;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;;;;(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;6*+1;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;3*-1/p-3

InChI key

GVSXYXXCIUVHQT-UHFFFAOYSA-K

Application

Reactant for synthesis of:
  • Supramolecular hydrogen-bonded Archimedean cages with encapsulated organic and inorganic species

Reactant for:
  • Temperature programmed reduction and hydrogen-isotope exchange
  • Passivation of stainless steel

Used for:
  • Plastic membrane electrodes for determination of flavoxate hydrochloride and cyclopentolate hydrochloride
  • Investigations of catalyst load role on transesterification of di-Me carbonate and phenol
  • Cocatalyst for methanol carbonylation


Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Hajime Katano et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 27(10), 1043-1047 (2011-10-12)
New appropriate reaction system was found for spectrophotometric determination of phosphate anion. This spectrophotometric method is based on the color development due to the formation of yellow molybdophosphate anion in acidic ethylene glycol-water (EG-W) mixed solution containing Mo(VI) species. The
Juan Feng et al.
Analytical biochemistry, 409(1), 144-149 (2010-10-26)
The classical malachite green (MLG) assay of phosphate, which added MLG after molybdate to the acidified reaction solutions of phosphate, tolerated interference from papaverine, sildenafil, and some similar hydrophobic amines. Resonance Rayleigh scattering signals, the alleviation of interference by poly(vinyl
Andrey V Bulatov et al.
Talanta, 96, 62-67 (2012-07-24)
Simple, rapid and fully automated methods for the manual and automated spectrophotometric determination of epinephrine have been developed by using schemes of stepwise injection (SWIA) and sequential injection analysis (SIA) implemented in the same manifold. The determination is based on



Global Trade Item Number

SKUGTIN
79558-100G04061833381427