1.12393
Vanadium(III) chloride
99+
Synonym(s):
Vanadium(III) chloride, Vanadium trichloride
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About This Item
Empirical Formula (Hill Notation):
Cl3V
CAS Number:
Molecular Weight:
157.30
UNSPSC Code:
12352302
EC Index Number:
231-744-6
NACRES:
NA.22
MDL number:
Form:
solid
Quality Level
form
solid
potency
350 mg/kg LD50, oral (Rat)
density
3.0 g/cm3 at 20 °C
bulk density
1000 kg/m3
storage temp.
no temp limit
SMILES string
[V](Cl)(Cl)Cl
InChI
1S/3ClH.V/h3*1H;/q;;;+3/p-3
InChI key
HQYCOEXWFMFWLR-UHFFFAOYSA-K
Application
Vanadium(III) chloride (VCl3) can be used as a catalyst to synthesize:
VCl3 can also be used as a reducing agent to determine nitrates and nitrites in water samples.
- Dihydropyrimidinone derivatives via a three-component Biginelli condensation reaction between aldehyde, β-keto ester, and urea (thiourea).
- Coumarin derivatives via Pechmann condensation reaction of various phenols and β-keto esters.
- β-amino alcohols by deprotection of epoxides with aromatic amines.
- Diol derivatives by chemoselective cleavage of acetonides in methanol.
VCl3 can also be used as a reducing agent to determine nitrates and nitrites in water samples.
Analysis Note
Assay (complexometric): ≥ 99.0 %
Identity (ICP-OES): passes test
Identity (ICP-OES): passes test
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Danger
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
supp_hazards
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
hcodes
Storage Class
8B - Non-combustible corrosive hazardous materials
Regulatory Information
危险化学品
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Certificates of Analysis (COA)
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Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Vanadium (III) chloride as an effective catalyst for the Pechmann reaction
Kumar BS, et al.
Chemistry of Heterocyclic Compounds, 42(2), 172-175 (2006)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 1123930025 | 04022536142364 |
| 1123931000 | 04022536142371 |