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Merck
CN

15238

BSTFA

derivatization grade (GC derivatization), LiChropur, contains 1% TMCS, 99% (excluding TMCS)

Synonym(s):

Silylating mixture V, BSTFA + TMCS

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About This Item

Linear Formula:
CF3C[=NSi(CH3)3]OSi(CH3)3
CAS Number:
Molecular Weight:
257.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
41116105
MDL number:
Beilstein/REAXYS Number:
2050024
Assay:
≥98.5% (excluding chlorotrimethylsilane, GC), 99% (excluding TMCS)
Form:
liquid
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Product Name

N,O-Bis(trimethylsilyl)trifluoroacetamide with trimethylchlorosilane, derivatization grade (GC derivatization), LiChropur, contains 1% TMCS, 99% (excluding TMCS)

grade

derivatization grade (GC derivatization)

Quality Level

assay

≥98.5% (excluding chlorotrimethylsilane, GC), 99% (excluding TMCS)

form

liquid

quality

LiChropur, contains 1% TMCS

reaction suitability

reagent type: derivatization reagent
reaction type: Silylations

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.384 (lit.)

bp

45-50 °C/14 mmHg (lit.)

density

0.97 g/mL (lit.)

SMILES string

C[Si](C)(C)O\C(=N\[Si](C)(C)C)C(F)(F)F

InChI

1S/C8H18F3NOSi2/c1-14(2,3)12-7(8(9,10)11)13-15(4,5)6/h1-6H3/b12-7+

InChI key

XCOBLONWWXQEBS-KPKJPENVSA-N

Application

Learn more in the Product Information

Packaging

Clear borosilicate glass, high hydrolytic resistance (Type I)

Other Notes

Silylating mixture used for the silylation of various compounds
The position of the silyl groups has not been unequivocally established. It has been referred to as both N,N and N,O.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

44.1 °F - closed cup

flash_point_c

6.7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Articles

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

Related Content


W.M. Hammargren et al.
Analytica Chimica Acta, 247, 201-201 (1991)
W. Greenway et al.
Journal of Chromatography A, 519, 145-145 (1990)
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)



Global Trade Item Number

SKUGTIN
947008-25G04065273972634
947008-100G04065273972627
15238-1ML04061837683510
15238-1ML-KC04061837683176
15238-25ML04061837683527
15238-0.1ML04061837683480
15238-100ML04061837683497
15238-10X0.1ML04061837683503
15238-10X1ML04061838740328
15238-5ML04061837683534