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Merck
CN

52864

Sodium 1-hexanesulfonate solution

suitable for ion pair chromatography, concentrate, LiChropur, ampule

Synonym(s):

1-Hexanesulfonic acid sodium salt

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About This Item

Linear Formula:
CH3(CH2)4CH2SO3Na
CAS Number:
Molecular Weight:
188.22
UNSPSC Code:
23151816
NACRES:
NB.21
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3727014
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description

anionic

Quality Level

quality

LiChropur, ampule

packaging

ampule of 25 mL

technique(s)

ion pair chromatography: suitable

λ

in concentrate

UV absorption

λ: 210 nm Amax: 0.07, λ: 220 nm Amax: 0.04, λ: 230 nm Amax: 0.03, λ: 260 nm Amax: 0.01, λ: 500 nm Amax: 0.01

suitability

corresponds to standard for RP gradient test, corresponds to standard for filter test

SMILES string

[Na+].CCCCCCS([O-])(=O)=O

InChI

1S/C6H14O3S.Na/c1-2-3-4-5-6-10(7,8)9;/h2-6H2,1H3,(H,7,8,9);/q;+1/p-1

InChI key

QWSZRRAAFHGKCH-UHFFFAOYSA-M

General description

Concentrate for 6x1 L ready-to-use solution. Dilute contents of one ampule (~0.3 M) to 1 L with HPLC grade water to obtain a 0.005 M eluent solution.

Application

Sodium 1-hexanesulfonate may be used as an ion-pairing reagent for the determination of L-carnitine in food supplement formulations by ion-pair chromatography with indirect conductimetric detection.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany


Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves



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Determination of L-carnitine in food supplement formulations using ion-pair chromatography with indirect conductimetric detection
Kakou A, et al.
Journal of Chromatography A, 1069(2), 209-215 (2005)
Kirti S Niralwad et al.
Ultrasonics sonochemistry, 17(5), 760-763 (2010-03-17)
1-Hexanesulphonic acid sodium salt was found to be an efficient catalyst for the green synthesis of alpha-aminophosphonates by the coupling of aldehydes/ketone, an amine and triethyl phosphite under ultrasound irradiation at ambient temperature for appropriate time to furnish the desired
Philip Zakaria et al.
Electrophoresis, 23(17), 2821-2832 (2002-09-11)
The separation of a series of aromatic carboxylic acids, sulfonates and opiates using electrokinetic chromatography employing a mixture of the soluble cationic polymer poly(diallydimethylammonium chloride) (PDDAC) and the amphiphilic anion hexanesulfonate as pseudostationary phases is described. In this system, the



Global Trade Item Number

SKUGTIN
52864-1AMP-F04061826696033
52864-6X1AMP-F04061833328521