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Merck
CN

31119

Ammonium sulfate

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99%

Synonym(s):

Mascagnite

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About This Item

Linear Formula:
(NH4)2SO4
CAS Number:
Molecular Weight:
132.14
PubChem Substance ID:
eCl@ss:
38030408
UNSPSC Code:
12352300
NACRES:
NA.21
EC Number:
231-984-1
MDL number:
Assay:
≥99%
Form:
crystals
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Quality Level

agency

USP/NF, reag. ISO, reag. Ph. Eur.

grade

ACS reagent, puriss. p.a.

assay

≥99%

form

crystals

impurities

≤0.005% in water insoluble matters, ≤5 ppm heavy metals (by ICP-OES)

ign. residue

≤0.005% (as SO4)

loss

≤0.1% loss on drying, 110 °C

pH

5-6 (25 °C, 5%)

mp

>280 °C (dec.) (lit.)

density

1.77 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤3 mg/kg, nitrate (NO3-): ≤10 mg/kg, phosphate (PO43-): ≤5 mg/kg

cation traces

As: ≤0.2 mg/kg, Ca: ≤10 mg/kg, Cd: ≤1 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤2 mg/kg, Fe: ≤2 mg/kg, K: ≤50 mg/kg, Mg: ≤2 mg/kg, Mn: ≤5 mg/kg, Na: ≤20 mg/kg, Ni: ≤5 mg/kg, Pb: ≤2 mg/kg, Zn: ≤1 mg/kg

SMILES string

N.N.OS(O)(=O)=O

InChI

1S/2H3N.H2O4S/c;;1-5(2,3)4/h2*1H3;(H2,1,2,3,4)

InChI key

BFNBIHQBYMNNAN-UHFFFAOYSA-N

General description

Ammonium sulfate is a versatile inorganic salt commonly used as an agriculture fertilizer as a nitrogen and sulfur source. It is also used as an extracting agent to extract metals such as iron, chromium, aluminum, and calcium. Furthermore, ammonium sulfate is employed in the purification of antibodies either from serum or ascitic fluids and in precipitating or fractionating proteins.

Application

Ammonium sulfatecan be used as a reagent in the palladium-catalyzed amination of aryl halidesto arylamines in the presence of sodium tert-butoxide. It can also beused as a catalyst in the hexamethyldisilazane-mediated reaction ofquinazolin-4(3H)-ones with primary amines to synthesize 4-aminoquinazolines.


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Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Deliquescence and crystallization of ammonium sulfate particles internally mixed with water-soluble organic compounds
Parsons MT, et al.
The Journal of Physical Chemistry A, 108(52), 11600-11608 (2004)



Global Trade Item Number

SKUGTIN
31119-5KG04061835562183
31119-1KG04061826681398
31119-4X5KG04061833030714