Merck
CN

234923

Sigma-Aldrich

丙烯酸丁酯

≥99%, contains 10-60 ppm monomethyl ether hydroquinone as inhibitor

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别名:
n-Butyl acrylate
线性分子式:
CH2=CHCOO(CH2)3CH3
CAS号:
分子量:
128.17
Beilstein:
1749970
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

蒸汽密度

>1 (vs air)

质量水平

蒸汽压

3.3 mmHg ( 20 °C)

检测方案

≥99%

形式

liquid

自燃温度

559 °F

包含

10-60 ppm monomethyl ether hydroquinone as inhibitor

expl. lim.

9.9 %

折射率

n20/D 1.418 (lit.)

bp

145 °C (lit.)

密度

0.894 g/mL at 25 °C (lit.)

SMILES字符串

CCCCOC(=O)C=C

InChI

1S/C7H12O2/c1-3-5-6-9-7(8)4-2/h4H,2-3,5-6H2,1H3

InChI key

CQEYYJKEWSMYFG-UHFFFAOYSA-N

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一般描述

丙烯酸丁酯是一种透明无色液体。这是一种乙烯基单体。它与含有乙烯基的苯并恶嗪进行自由基共聚,以制备共聚物。已有报道关于由膦基咪唑盐介导的芳基溴代与丙烯酸丁酯的偶联反应。已有介绍关于在CuBr/4,4′-二(5-壬基)-2,2′-二吡啶的催化下,ATRP催化苯乙烯与丙烯酸丁酯的共聚反应。

应用

丙烯酸丁酯用于制备:
  • 聚(丙烯酸丁酯)粒子。
  • 聚丙烯酸丁酯-b-丙烯酸嵌段共聚物。
  • 两亲性带电双嵌段共聚物聚(丙烯酸丁酯)-b-聚(丙烯酸)。
  • 在CuIBr/4,4′-二(5-壬基)-2,2′-双吡啶(催化剂)存在下,共聚物(丙烯酸丁酯)通过原子转移自由基聚合(ATRP)合成丙烯酸丁酯。

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

98.6 °F - closed cup

闪点(°C)

37 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Conducting polyaniline composite: From syntheses in waterborne systems to chemical sensor devices
Joubert M, et al.
Polymer, 51(8), 1716-1722 (2010)
Atom transfer radical copolymerization of styrene and n-butyl acrylate.
Arehart SV and Matyjaszewski K.
Macromolecules, 32(7), 2221-2231 (1999)
M Jacquin et al.
Journal of colloid and interface science, 316(2), 897-911 (2007-10-02)
We have linked the structural and dynamic properties in aqueous solution of amphiphilic charged diblock copolymers poly(butyl acrylate)-b-poly(acrylic acid), PBA-b-PAA, synthesized by controlled radical polymerization, with the physico-chemical characteristics of the samples. Despite product imperfections, the samples self-assemble in melt
Tsutomu Takeichi et al.
Molecules (Basel, Switzerland), 20(4), 6488-6503 (2015-04-14)
A benzoxazine containing a vinyl group (P-4va) was prepared by the reaction of phenol, 4-vinylaniline, and paraformaldehyde. A differential scanning calorimetry (DSC) study revealed that ring-opening polymerization of the benzoxazine and chain polymerization of the vinyl group occurred in the
C Yang et al.
Organic letters, 3(10), 1511-1514 (2001-06-05)
[reaction: see text] A new phosphine-imidazolium salt, L.HBr (1, L = (1-ethylenediphenylphosphino-3-(mesityl))imidazol-2-ylidene), has been prepared. A combination of 0.5 mol % of Pd(dba)(2) and 0.5 mol % of L.HBr in the presence of 2 equiv of Cs(2)CO(3) as base has

商品

The manufacture of monomers for use in ophthalmic applications is driven by the need for higher purity, improved reliability of manufacturing supply, but ultimately by the need for the increased comfort, convenience, and safety of contact lens wearers. Daily wear contact lenses have the potential to fill this need for many customers; however, their widespread use is constrained by higher costs compared to weekly- or monthly-based lenses. New approaches that improve cost structure and result in higher quality raw materials are needed to help make contact lenses more affordable and accelerate growth of the contact lens market.

The manufacture of monomers for use in ophthalmic applications is driven by the need for higher purity, improved reliability of manufacturing supply, but ultimately by the need for the increased comfort, convenience, and safety of contact lens wearers. Daily wear contact lenses have the potential to fill this need for many customers; however, their widespread use is constrained by higher costs compared to weekly- or monthly-based lenses. New approaches that improve cost structure and result in higher quality raw materials are needed to help make contact lenses more affordable and accelerate growth of the contact lens market.

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

Heck反应是烯烃与芳基或乙烯基卤化物(或三氟甲磺酸酯)之间的钯催化交叉偶联反应,用于生成取代的烯烃。

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