Merck
CN

M55909

Sigma-Aldrich

甲基丙烯酸甲酯

contains ≤30 ppm MEHQ as inhibitor, 99%

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别名:
2-甲基-2-丙烯酸甲酯, 甲基-2-丙烯酸甲酯, 甲基丙烯酸甲酯
线性分子式:
CH2=C(CH3)COOCH3
CAS号:
分子量:
100.12
Beilstein:
605459
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

蒸汽密度

3.5 (vs air)

质量水平

蒸汽压

29 mmHg ( 20 °C)

检测方案

99%

自燃温度

815 °F

包含

≤30 ppm MEHQ as inhibitor

expl. lim.

12.5 %

折射率

n20/D 1.414 (lit.)

bp

100 °C (lit.)

mp

−48 °C (lit.)

密度

0.936 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

COC(=O)C(C)=C

InChI

1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3

InChI key

VVQNEPGJFQJSBK-UHFFFAOYSA-N

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一般描述

甲基丙烯酸甲酯是重要的化工单体和构筑 单元,用于丙烯基聚合物的制备。它是多种聚合物的优良溶剂, 带来高粘接强度。

应用

甲基丙烯酸甲酯可用作单体:
  • 制备基于甲基丙烯酸甲酯的互穿聚合物网络,热学和力学性能增强。
  • 通过乳液共聚反应制备聚甲基丙烯酸甲酯共甲基丙烯酸羟乙酯(PMMA-co-PHEMA)共聚物,共聚物形成热氧稳定性、柔性膜。
  • 制备镧系配合物接枝聚甲基丙烯酸甲酯共马来酸酐共聚物。这种发光聚合物具有高热稳定性,可用作光电装置的发光层。
  • 通过微量微乳液聚合(differential microemulsion polymerization)技术制备聚甲基丙烯酸甲酯纳米颗粒。

象形图

FlameExclamation mark

警示用语:

Danger

危险分类

Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

50.0 °F - closed cup

闪点(°C)

10 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Daniel S Thoma et al.
Journal of periodontal & implant science, 49(3), 171-184 (2019-07-10)
To evaluate the effects of intra-alveolar socket grafting, subepithelial connective tissue grafts, and individualized abutments on peri-implant hard and soft tissue outcomes following immediate implant placement. This randomized experimental study employed 5 mongrel dogs, with 4 sites per dog (total
J Ratliff et al.
Spine, 26(13), E300-E302 (2001-07-18)
Case report and literature review. Clinicians use methylmethacrylate vertebroplasty to treat vertebral hemangiomas, metastases, and osteoporotic fractures. Cement may leak out of the vertebral body and compress the adjacent spinal cord and nerve roots. We review a case of nerve-root
Michael M Bornstein et al.
Journal of endodontics, 41(6), 804-811 (2015-04-13)
The aim of this study was to evaluate the concordance of 2- and 3-dimensional radiography and histopathology in the diagnosis of periapical lesions. Patients were consecutively enrolled in this study provided that preoperative periapical radiography (PR) and cone-beam computed tomographic
Kevin N Johnson et al.
The Annals of thoracic surgery, 99(6), 1936-1943 (2015-04-30)
Successful repair of recurrent pectus excavatum (PE) after failed open procedure has been reported using minimally invasive repair (MIRPE) and open approaches. Neither approach alone may be adequate for some patients. A hybrid technique for repair is presented for revision
Fabrice Audouin et al.
Biomacromolecules, 13(11), 3787-3794 (2012-10-20)
Amino-functional macroporous monoliths from polymerized high internal phase emulsion (polyHIPE) were surface modified with initiators for atom transfer radical polymerization (ATRP). The ATRP initiator groups on the polyHIPE surface were successfully used to initiate activator regeneration by electron transfer (ARGET)

商品

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

The manufacture of monomers for use in ophthalmic applications is driven by the need for higher purity, improved reliability of manufacturing supply, but ultimately by the need for the increased comfort, convenience, and safety of contact lens wearers. Daily wear contact lenses have the potential to fill this need for many customers; however, their widespread use is constrained by higher costs compared to weekly- or monthly-based lenses. New approaches that improve cost structure and result in higher quality raw materials are needed to help make contact lenses more affordable and accelerate growth of the contact lens market.

The manufacture of monomers for use in ophthalmic applications is driven by the need for higher purity, improved reliability of manufacturing supply, but ultimately by the need for the increased comfort, convenience, and safety of contact lens wearers. Daily wear contact lenses have the potential to fill this need for many customers; however, their widespread use is constrained by higher costs compared to weekly- or monthly-based lenses. New approaches that improve cost structure and result in higher quality raw materials are needed to help make contact lenses more affordable and accelerate growth of the contact lens market.

实验方案

We presents an article about ARGET ATRP, and its procedure for PMMA polymer brush growth. Surface preparation before polymer brush growth consists of two steps: surface cleaning and initiator monolayer deposition.

We presents an article about ARGET ATRP, and its procedure for PMMA polymer brush growth. Surface preparation before polymer brush growth consists of two steps: surface cleaning and initiator monolayer deposition.

Monodisperse, surfactant-free polymer spheres for use as colloidal crystal templates can be easily obtained in reasonably large quantities. Typical synthesis methods for poly(methyl methacrylate) (PMMA) and poly(styrene) (PS) by emulsifier free emulsion polymerization are described below and yield spheres several hundred nanometers in diameter.

Monodisperse, surfactant-free polymer spheres for use as colloidal crystal templates can be easily obtained in reasonably large quantities. Typical synthesis methods for poly(methyl methacrylate) (PMMA) and poly(styrene) (PS) by emulsifier free emulsion polymerization are described below and yield spheres several hundred nanometers in diameter.

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