Merck
CN

254169

Sigma-Aldrich

氯化金 (III) 水合物

99.995% trace metals basis

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别名:
四氯金酸, 四氯金酸氢 水合物, 氯化金, 氯金酸
线性分子式:
HAuCl4 · aq
CAS号:
分子量:
339.79 (anhydrous basis)
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

检测方案

99.995% trace metals basis

形式

crystals and lumps

组成

Degree of hydration, ~3

反应适用性

reagent type: catalyst
core: gold

技术

ELISA: suitable

杂质

≤55.0 ppm Trace Metal Analysis

密度

3.9 g/mL at 25 °C

SMILES字符串

O.Cl.Cl[Au](Cl)Cl

InChI

1S/Au.4ClH.H2O/h;4*1H;1H2/q+3;;;;;/p-3

InChI key

OVJUDSKPNIBLOO-UHFFFAOYSA-K

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一般描述

氯化金(III)水合物(HAuCl4)可用作合成金纳米颗粒和大多数共轭有机分子的 p 型掺杂剂的前体。.掺杂导致晶格膨胀,并由于大量电荷载流子的形成而增强导电性。

应用

氯化金(III)水合物可用于通过与尿素的沉积沉淀来制备 TiO2负载的 Au 基光催化剂。这些催化剂在水裂解反应中表现出较高的产氢量和产氢速率。

共轭聚噻吩膜可以通过使用 HAuCl4 作为掺杂剂的溶液掺杂方法来制备。这些高导电聚合物薄膜可应用于蒸汽传感和有机电子领域。

通过使用不同的还原剂,如 NaBH4、葡萄糖和聚(丙烯亚胺)树枝状聚合物,可以通过还原 HAuCl4来制备金纳米颗粒。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT RE 2 Oral

靶器官

Kidney

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


分析证书(COA)

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索取COA

  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How can I determine the number of hydrates present in Product 254169, Gold (III) chloride hydrate?

    To determine the number of hydrates, you can use the following formula:   % of the metal = [(MW of metal) (# of metal atoms)] / [(MW of anhydrous product) + (x * 18g/mol)]Solving for x: x = [[(MW of metal)(#metal atoms)] - [(%of metal in product)(MW of anhydrous product)]] / [(% of metal in product) (18 g/mol)] 

  4. What is n Product 254169, Gold (III) chloride hydrate soluble in?

    This product is soluble in water, ethanol, and ether.  Unfortunately we do not have any recorded concentrations.

  5. What is the melting point of n Product 254169, Gold (III) chloride hydrate?

    We have never determined the melting point, however we do have a note indicating that this compound will decompose when melted.  Also the 13th Edition of the chemicals encyclopedia published by the Royal Society of Chemistry states that this compound will decompose on strong heating to form chlorine gas, hydrochloric acid gas, and metallic gold.

  6. What is the reported purity of Product 254169, Gold (III) chloride hydrate based on, chemical or metal purity?

    The purity (99.999%) is not the chemical purity, but rather the purity based on trace metal content.  In the case of 99.999% a maximum of 20ppm total metallic impurities would be allowed.

  7. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  8. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  9. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Bo Chuan Huang et al.
Scientific reports, 9(1), 7589-7589 (2019-05-22)
Shewanella oneidensis MR-1, a bioelectricity generating bacterium, is broadly used in bioremediation, microbial fuel cell and dissimilatory reduction and recovery of precious metals. Herein, we report for the first time that photo induction as a trigger to stimulate gold nanoparticles
Fink, J. et al.
Chemistry of Materials, 10, 922-922 (1998)
Ligand-induced gold nanocrystal superlattice formation in colloidal solution.
Lin XM, et al.
Chemistry of Materials, 11(2), 198-202 (1999)
The crystal structure of gold(III) chloride.
Clark ES, et al.
Acta Crystallographica, 11, 284-288 (1958)
Motao Zhu et al.
ACS nano, 14(3), 3703-3717 (2020-02-15)
Engineered nanoparticles could trigger inflammatory responses and potentiate a desired innate immune response for efficient immunotherapy. Here we report size-dependent activation of innate immune signaling pathways by gold (Au) nanoparticles. The ultrasmall-size (<10 nm) Au nanoparticles preferentially activate the NLRP3

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