vapor density
5.25 (vs air)
vapor pressure
13 hPa ( 20 °C)
assay
≥99%
form
liquid
refractive index
n20/D 1.368 (lit.)
bp
121-122 °C (lit.)
mp
−4 °C (lit.)
density
1.023 g/mL at 25 °C (lit.)
SMILES string
CO[Si](OC)(OC)OC
InChI
1S/C4H12O4Si/c1-5-9(6-2,7-3)8-4/h1-4H3
InChI key
LFQCEHFDDXELDD-UHFFFAOYSA-N
General description
正硅酸甲酯是无色的有机硅化合物，由四个甲基连接硅原子而成。 水解产生二氧化硅和甲醇。广泛用于催化、纳米材料合成、陶瓷、沸石和涂料。
Application
正硅酸甲酯可用于：
- 作为前体通过溶胶-凝胶法合成 有机-无机涂料。
- 作为高效的反应试剂，用于 脂肪族羧酸和芳香族羧酸与胺和苯胺的直接酰胺化反应。
- As 前体，通过化学气相沉积法(CVD)制造SiO2纳米复合薄膜。
- 作为吲哚进行C3-甲基化反应的催化剂。
用于掺铬硅酸盐的溶胶-凝胶合成以及六方介孔氧化硅层的形成。
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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商品
涉及到反应性有机硅化学的研究已聚焦于纯硅和杂合材料的生产、氢化硅烷化、开环和原子转移聚合，以及具有受控立体化学的聚合和缩合反应。
Silica's versatility spans various industries, including biomedical applications.
Reactive silicone chemistry: Focus on pure silicon production, polymerizations, and controlled stereochemistry reactions.
Yun Tian et al.
Electrophoresis, 29(4), 960-970 (2008-01-24)
A novel calix[4] open-chain crown ether (p-tert-butylcalix[4]arene-1,3-bis(allyloxyethy) ether)-modified, organic-inorganic hybrid silica-based monolithic column possessing vinyl ligands for CEC is described. The monolithic silica matrix containing a vinyl functionality was synthesized by in situ cocondensation of tetramethoxysilane (TMOS) and vinyltrimethoxysilane (VTMS)
Yonghao Xiu et al.
Journal of colloid and interface science, 326(2), 465-470 (2008-07-29)
A method for the preparation of inorganic superhydrophobic silica coatings using sol-gel processing with tetramethoxysilane and isobutyltrimethoxysilane as precursors is described. Incorporation of isobutyltrimethoxysilane into silica layers resulted in the existence of hydrophobic isobutyl surface groups, thereby generating surface hydrophobicity.
Akhilesh Rai et al.
Langmuir : the ACS journal of surfaces and colloids, 26(6), 4152-4159 (2009-12-17)
We report an elegant and simple method to fabricate uniform silica films with controlled thickness, roughness, and hydrophilicity using nanogram quantities of silicatein, a protein involved in silica synthesis in sponges. The formation of uniform silica films was achieved by
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 341436-100G | 04061826754016 |
| 341436-25G | 04061826754023 |