673293
五甲基环戊二烯基双(三苯基膦)氯化钌(II)
solid
别名:
Cp*RuCl(PPh3)2, 氯(五甲基环戊二烯基)双(三苯基膦)合钌(II)
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关于此项目
线性分子式:
[(C10H15)Ru(P((C6H5)3))2Cl]
化学文摘社编号:
分子量:
796.32
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
五甲基环戊二烯基双(三苯基膦)氯化钌(II),
form
solid
Quality Level
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: click chemistry
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
128 °C (D)
greener alternative category
storage temp.
2-8°C
SMILES string
Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
InChI
1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1
InChI key
KLXKSZDVKAWYRT-UHFFFAOYSA-M
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a versatile catalyst for regioselective 3+2 cycloaddition of azides and alkynes (RuAAC), producing 1,5-disubstituted triazoles. Click here for more information.
Application
叠氮化物与乙炔环加成反应的催化剂，专一性生成 1,5-二取代三唑，相比之下，常见的铜催化则具有 1,4-区域选择性。钌催化还使得可在此类"点击环加成反应"中使用内炔。
活性自由基聚合反应的多功能催化剂
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
Explore click chemistry: efficient, high-yield reactions for drug discovery, bioconjugation, and green chemistry with simple conditions and wide applications.