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677264

APhos

Name: APhos
Brand: ALDRICH

95%, solid

别名:

(4-(N,N-二甲氨基)苯基)二-叔丁基膦, A-^taPhos, [4-（二甲氨基）苯基]双（叔丁基）苯基

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关于此项目

经验公式（希尔记法）:

C₁₆H₂₈NP

化学文摘社编号:

932710-63-9

分子量:

265.37

UNSPSC Code:

12352116

PubChem Substance ID:

24885360

NACRES:

NA.22

MDL number:

MFCD09265102

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属性

产品名称

APhos, 95%

Quality Level

100

assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reagent type: ligand
reaction type: Cross Couplings

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

57-61 °C

functional group

phosphine

greener alternative category

Aligned

SMILES string

CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C

InChI

1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3

InChI key

IQTHEAQKKVAXGV-UHFFFAOYSA-N

说明

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is the APHOS ligand system for asymmetric catalysis, providing high enantioselectivity in various metal-catalyzed transformations. Click here for more information.

Application

用于制备处理 PdCl₂ (COD) 所用的二氯化钯催化剂 (678740) 的配体。该催化剂使芳基硼酸与杂芳基氯化物高效交联。

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pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P305 + P351 + P338 - P310

Hazard Classifications

Skin Corr. 1B

存储类别

8B - Non-combustible, corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c