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双[(2-二甲氨基)苯基]胺氯化镍(II)

Name: 双[(2-二甲氨基)苯基]胺氯化镍(II)
Brand: ALDRICH

≥97% (AT), lumps

别名:

Nickamine, 氯[N²-[2-(二甲氨基-κN)苯基]-N¹,N¹-二甲基-1,2-苯二胺-κN¹,κN²]-镍

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关于此项目

经验公式（希尔记法）:

C₁₆H₂₀ClN₃Ni

化学文摘社编号:

1033772-47-2

分子量:

348.50

UNSPSC Code:

12161600

PubChem Substance ID:

329764408

NACRES:

NA.22

MDL number:

MFCD17015253

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属性

产品名称

双[(2-二甲氨基)苯基]胺氯化镍(II), ≥97% (AT)

Quality Level

200

assay

≥97% (AT)

form

lumps

reaction suitability

core: nickel, reagent type: catalyst

SMILES string

CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C

InChI

1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1

InChI key

IRLHVNUEEKJBEL-UHFFFAOYSA-M

说明

Application

Catalyst for:

Alkyl-alkyl Kumada coupling of secondary alkyl halides
Direct alkylation of heterocyclic C-H bonds
Sonogashira coupling of nonactivated alkyl halides
Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles

Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.