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Merck
CN

740810

2-(十二烷基硫基硫代羰基硫基)-2-甲基丙酸五氟苯基酯

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关于此项目

经验公式(希尔记法):
C23H31F5O2S3
化学文摘社编号:
分子量:
530.68
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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form

liquid

impurities

4-5% pentafluorophenol

refractive index

n20/D 1.512

density

1.203 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)Oc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C23H31F5O2S3/c1-4-5-6-7-8-9-10-11-12-13-14-32-22(31)33-23(2,3)21(29)30-20-18(27)16(25)15(24)17(26)19(20)28/h4-14H2,1-3H3

InChI key

XBUCQRRMAZYXHN-UHFFFAOYSA-N

General description

需要帮助选择正确的RAFT试剂?请查阅RAFT试剂与单体的相容性表。

Application

用于受控自由基聚合的RAFT试剂,特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。链转移剂(CTA)

Other Notes

该产品含有4-5%的五氟苯酚杂质。 该杂质通常不会干扰链转移剂


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

>230.0 °F

flash_point_c

> 110 °C



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

商品

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.


RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being



全球贸易项目编号

货号GTIN
740810-1G04061826280782
740810-5G04061832978369