790753
(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-disulfonimide
95%
别名:
(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
选择尺寸
关于此项目
assay
95%
form
solid
optical activity
[α]22/D -42.0°, c = 0.5% in chloroform
reaction suitability
reaction type: Aldol Reaction, reaction type: Allylation, reaction type: Carbonyl/Imine Addition, reaction type: Friedel-Crafts Alkylation
mp
325-330 °C
SMILES string
FC(F)(F)c1cc(cc(c1)C(F)(F)F)-c2cc3ccccc3c4-c5c(c(cc6ccccc56)-c7cc(cc(c7)C(F)(F)F)C(F)(F)F)S(=O)(=O)NS(=O)(=O)c24
InChI
1S/C36H17F12NO4S2/c37-33(38,39)21-9-19(10-22(15-21)34(40,41)42)27-13-17-5-1-3-7-25(17)29-30-26-8-4-2-6-18(26)14-28(32(30)55(52,53)49-54(50,51)31(27)29)20-11-23(35(43,44)45)16-24(12-20)36(46,47)48/h1-16,49H
InChI key
DFXCMPXSCANWFA-UHFFFAOYSA-N
Application
A Powerful Chiral Counteranion Motif for Asymmetric Catalysis
Chiral Sulfonimide as a Brønsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines
Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
此项目有
商品
Asymmetric counteranion-directed catalysis (ACDC) has a number of valuable applications in enantioselective synthesis.
相关内容
The List group focuses on the development of new concepts in catalysis. Since 1999, this research group has pioneered the development of organocatalysis as the third pillar of stereoselective catalysis, along side biocatalysis and transition metal catalysis.