798371
Exo-Phenyl Kwon [2.2.1]双环膦
95% (HPLC)
别名:
(1S,4S,5R)-5-(phenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
选择尺寸
关于此项目
Quality Level
assay
95% (HPLC)
form
powder
storage condition
under inert gas
mp
158-162 °C
functional group
phosphine, sulfonamide
storage temp.
2-8°C
SMILES string
CC1=CC=C(S(N2C[C@@]3([H])[P@](C4=CC=CC=C4)C[C@]2([H])C3)(=O)=O)C=C1
InChI
1S/C18H20NO2PS/c1-14-7-9-18(10-8-14)23(20,21)19-12-17-11-15(19)13-22(17)16-5-3-2-4-6-16/h2-10,15,17H,11-13H2,1H3
InChI key
BWXYDSDVFPJTFY-UHFFFAOYSA-N
Application
Other Notes
Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline
Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
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signalword
Warning
hcodes
pcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
商品
Chiral phosphines have been the staple ligands for asymmetric transition metal catalysis and more recently operate as catalysts in organic phosphinocatalysis.
相关内容
The Kwon Group has made major strides in the development and application of nucleophilic phosphinocatalysis reactions as a means to synthesize carbo- and heterocycles that serve as synthetic intermediates for both natural products and medicinally useful compounds.