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911208

1-Hydrosilatrane

≥95%

别名:

Hydrosilatrane, Silatrane

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关于此项目

经验公式（希尔记法）:
C6H13NO3Si
化学文摘社编号:
283-60-3
分子量:
175.26
MDL number:
MFCD22056310
UNSPSC Code:
41116107
NACRES:
NA.22
Assay:
≥95%
Form:
powder or crystals
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assay

≥95%

form

powder or crystals

reaction suitability

reagent type: reductant

mp

249-256 °C

storage temp.

−20°C

InChI

1S/C6H12NO3Si/c1-4-8-11-9-5-2-7(1)3-6-10-11/h1-6H2

InChI key

XBRVPWBNRAPVCC-UHFFFAOYSA-N

Application

1-Hydrosilatrane is an air- and moisture-stable hydride reducing reagent that exhibits high functional group compatibility. The Adler group has used 1-hydrosilatrane for the reduction of ketones and aldehydes as well as the direct reductive amination of ketones under mild conditions.

Other Notes

Chiral Bronsted Acid-Catalyzed Metal-Free Asymmetric Direct Reductive Amination Using 1-Hydrosilatrane

Silatrane as a Practical and Selective Reagent for the Reduction of Aryl Aldehydes to Benzylic Alcohols

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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1-hydrosilatrane

As a versatile hydride reagent, 1-hydrosilatrane can be used in reduction reactions to synthesize alcohols, amines, their chiral counterparts, and esters from aldehydes/ketones.