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Merck
CN

61194

硝酸铜 三水合物

puriss. p.a., 99-104%

别名:

Cupric nitrate 三水合物

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关于此项目

线性分子式:
Cu(NO3)2 · 3H2O
化学文摘社编号:
分子量:
241.60
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
221-838-5
MDL number:
Assay:
99-104%
Form:
powder or crystals
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grade

puriss. p.a.

Quality Level

assay

99-104%

form

powder or crystals

anion traces

chloride (Cl-): ≤20 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Fe: ≤20 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤10 mg/kg, Pb: ≤10 mg/kg, Zn: ≤5 mg/kg

SMILES string

O.O.O.[Cu++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Cu.2NO3.3H2O/c;2*2-1(3)4;;;/h;;;3*1H2/q+2;2*-1;;;

InChI key

SXTLQDJHRPXDSB-UHFFFAOYSA-N

General description

硝酸铜 (II) 三水合物是一种水合铜盐。它作为催化剂可参与催化 3-氨基丙烯酮和 3-氨基丙烯酸酯的无溶剂合成。

Application

硝酸铜 (II) 三水合物可用于制备以下单核铜 (II) 配合物(phen = 1,10-邻菲罗啉,dpq = 二吡啶并 [3,2-d:2′,3'-f] 喹喔啉, dppz = 二吡啶并 [3,2-a:2′,3'-c] 吩嗪):
  • [Cu(dpq)(NO3)2]
  • [Cu(dpq)(NO3)(H2O)2](NO3)
  • [Cu(dpq)(NO3)2(H2O)2]·2H2O
  • [Cu(dppz)(NO3)2(H2O)]·H2O


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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品

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Anitha M Thomas et al.
Journal of inorganic biochemistry, 94(1-2), 171-178 (2003-03-07)
A series of mononuclear copper(II) complexes having a 1:1 molar ratio of copper and the planar heterocyclic base like 1,10-phenanthroline (phen), dipyrido[3,2-d:2',3'-f]quinoxaline (dpq) and dipyrido[3,2-a:2',3'-c]phenazine (dppz) are prepared from a reaction of copper(II) nitrate.trihydrate and the base (L) in ethanol
Simple and efficient synthesis of 3-aminopropenones and 3-aminopropenoates catalyzed by copper (II) nitrate trihydrate under solvent-free conditions.
Li GC.
Monatshefte fur Chemie / Chemical Monthly, 139(7), 789-792 (2008)
Zachary C Redman et al.
Journal of agricultural and food chemistry, 67(45), 12402-12407 (2019-10-31)
The hydrolysis of chlorantraniliprole (3-bromo-N-[4-chloro-2-methyl-6-(methylcarbamoyl)phenyl]-1-(3-chloro-2-pyridine-2-yl)-1H-pyrazole-5-carboxamide; CAP) was investigated over the pH range of 6-10, reflective of California rice field conditions, with variable additions of Cu2+, Zn2+, Mn2+, or Ni2+. Dissipation accelerated as pH increased with half-lives ranging from 26.9 to



全球贸易项目编号

货号GTIN
61194-500G04061832691114
61194-100G04061832691107